IONIC-CONDUCTIVITY SWITCHING OF VINYL MALACHITE GREEN LEUCONITRILE COPOLYMERS BASED ON PHOTOINDUCED CARRIER GENERATION

被引：10

作者：

KIMURA, K

KANESHIGE, M

TOKUHISA, H

YOKOYAMA, M

机构：

[1] Faculty of Engineering, Osaka University, Suita, Osaka, 565, Yamada‐oka

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1993年 / 31卷 / 11期

关键词：

MALACHITE GREEN VINYL POLYMER; IONIC CONDUCTIVITY; PHOTOINDUCED SWITCHING; SINGLE-IONIC; CARRIER GENERATION;

D O I：

10.1002/pola.1993.080311118

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Copolymers of bis[4-(NN-dimethylamino)phenyl]-4-vinylphenylmethanenitrile (vinyl Malachite Green leuconitrile) with methyl methacrylate or omega-methoxyoligo(oxyethylene) methacrylate have been synthesized, aiming at designing one-component-type organic polymers for photoswitchable ion-conducting films. The triphenylmethanenitrile copolymers with omega-methoxyoligo (oxyethylene) methacrylate were found to undergo ionic-conductivity switching by turning on and off UV light at ambient temperature, owing to their low glass transition temperature. (C) 1993 John Wiley & Sons, Inc.

引用

页码：2809 / 2813

页数：5

共 7 条

[1]

BERTELSON RC, 1971, TECHNIQUES CHEM, V3, pCH3

[2] PHOTORESPONSIVE IONIC-CONDUCTIVITY OF POLYMER COMPOSITE FILMS CONTAINING AZOBENZENE LIQUID-CRYSTAL [J].