TRANSITION-METAL SUBSTITUTED KEGGIN-TYPE POLYOXOMOLYBDATES AS BIFUNCTIONAL CATALYSTS FOR THE EPOXIDATION OF ALKENES BY MOLECULAR-OXYGEN

被引：47

作者：

NEUMANN, R

DAHAN, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 02期

关键词：

D O I：

10.1039/c39950000171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In a one-pot reaction, transition metal substituted polyoxomolybdates are shown to be bifunctional catalysts for epoxidation of alkenes by via oxygen transfer from intermediate alkylhydroperoxides; the latter being formed by catalytic autoxidation with molecular oxygen.

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页码：171 / 172

页数：2

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