We have synthesized the fulleride system SmxC60 (x<3). It is found that Sm can be intercalated into interstitial sites of C-60 to form a solid solution. For the nominal composition x=3, the sample shows superconductivity at T-c=8 K. X-ray diffraction reveals an orthorhombic structure with a=28.17(5) Angstrom, b=28.07(3) Angstrom, and c=28.27(3) Angstrom, derived from the face-centered cubic cell of A(3)C(60) by doubling in each direction and analogous to that of Yb2.75C60. The lattice parameters of Sm-doped C-60 are significantly larger than those of Yb-doped C-60 and the superconducting transition temperature of Sm3C60 is 2 K higher than that of Yb2.75C60.