PHOTODISSOCIATION OF CH3ONO BY A DIRECT AND INDIRECT MECHANISM

被引：26

作者：

SUTER, HU

BRUHLMANN, U

HUBER, JR

机构：

[1] Physikalisch-Chemisches Institut der Universität Zürich, CH-8057 Zurich

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 171卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(90)80051-E

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The S2 potential-energy surface of CH3ONO has been calculated for the coordinates RNO and RON using the MCSCF ab initio method. To complete the experimental data set of the S2 photodissociation, we have measured the vibrational- and rotational-state distributions of the NO(X 2Π) fragments, and discussed the distinctly different product energy distributions from the direct S2 and the indirect S1 dissociation on the basis of the potential-energy surfaces. © 1990.

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页码：63 / 67

页数：5

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