THE GROUND-STATE OF COAR(+)

被引：43

作者：

ASHER, RL ^{[1
]}

BELLERT, D ^{[1
]}

BUTHELEZI, T ^{[1
]}

BRUCAT, PJ ^{[1
]}

机构：

[1] UNIV FLORIDA,CTR CHEM PHYS,GAINESVILLE,FL 32611

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 227卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(94)00828-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rotationally resolved photodissociation spectra of CoAr+ have been observed for three different electronic transitions of the isolated ion. Analysis yields rotational constants and the angular momentum (spin plus orbit) for both states in the transition. The bond length of the vibrationless ground state of this ion is determined to be r0 = 2.385 +/- 0.005 angstrom consistent with a 3DELTA3 electronic state. Three assigned excited-state diabatic dissociation limits enable the accurate determination of the adiabatic binding energy of ground state of CoAr+ as D0 = 4111 +/- 5 cm-1. These values are discussed in comparison with recent ab initio theory.

引用

页码：277 / 282

页数：6

共 11 条

[1] THE BOND STRENGTH OF NI2+ [J].