SYNTHESIS OF BETA-FLUORO-ALPHA,BETA-UNSATURATED ESTERS AND NITRILES VIA A FLUORO-PUMMERER REARRANGEMENT

被引：18

作者：

KRISHNAN, G ^{[1
]}

SAMPSON, P ^{[1
]}

机构：

[1] KENT STATE UNIV,DEPT CHEM,KENT,OH 44242

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 39期

关键词：

D O I：

10.1016/S0040-4039(00)97909-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A 5-step synthesis of terminally unsaturated β-fluoro-α, β -unsaturated esters and nitriles 1 is described. Substantial amounts of a deoxygenative side reaction were observed during the key fluoro-Pummerer rearrangement step in the routes leading to the nitriles 1c and 1d. © 1990.

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页码：5609 / 5612

页数：4

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