(MU-ALKOXO)DIIRON(II,II) COMPLEXES OF N,N,N',N'-TETRAKIS(2-(6-METHYLPYRIDYL)METHYL)-1,3-DIAMINOPROPANE-2-OLATE AND THE REVERSIBLE FORMATION OF THE O2-ADDUCTS

被引：43

作者：

HAYASHI, Y

SUZUKI, M

UEHARA, A

MIZUTANI, Y

KITAGAWA, T

机构：

[1] KANAZAWA UNIV, FAC SCI, DEPT CHEM, KANAZAWA, ISHIKAWA 920, JAPAN

[2] INST MOLEC SCI, OKAZAKI, AICHI 444, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 01期

关键词：

D O I：

10.1246/cl.1992.91

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(mu-Alkoxo)(mu-carboxylato)diiron(II,II) complexes with hindered dinucleating ligand were synthesized and the structure of mu-benzoato derivative was determined by X-ray analysis. The complexes showed reversible oxygenation in acetonitrile and dichloromethane. Resonance Raman spectra of these species demonstrated a possibility of unsymmetrical mu-eta(1)-eta(1') binding of the oxygen toward the diiron centers.

引用

页码：91 / 94

页数：4

共 9 条

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