MECHANISM OF THE ACID-CATALYZED PATHWAY FOR THE NITROSATION OF HYDROXYLAMINE

被引：15

作者：

BOURKE, GCM ^{[1
]}

STEDMAN, G ^{[1
]}

机构：

[1] UNIV COLL SWANSEA,DEPT CHEM,SINGLETON PK,SWANSEA SA2 8PP,W GLAM,WALES

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 02期

关键词：

D O I：

10.1039/p29920000161

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The profile of rate constant versus [H+] for the acid catalysed pathway of the nitrous acid reaction with the hydroxyammonium ion can be quantitatively interpreted in terms of a reversible O-nitrosation, followed by an O to N migration of the nitroso group in the conjugate base species NH2ONO. There is no need to assume a non-steady-state mechanism involving NO+, as has been proposed previously.

引用

页码：161 / 162

页数：2

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