DENSITIES, EXCESS MOLAR VOLUMES, AND PARTIAL MOLAR VOLUMES FOR BINARY-MIXTURES OF WATER WITH MONOETHANOLAMINE, DIETHANOLAMINE, AND TRIETHANOLAMINE FROM 25-DEGREES-C TO 80-DEGREES-C

被引:158
作者
MAHAM, Y
TENG, TT
HEPLER, LG
MATHER, AE
机构
[1] UNIV ALBERTA,DEPT CHEM ENGN,EDMONTON T6G 2G2,ALBERTA,CANADA
[2] UNIV SCI MALAYSIA,SCH IND TECHNOL,GEORGE TOWN,MALAYSIA
关键词
DENSITIES; EXCESS AND PARTIAL MOLAR VOLUMES; BINARY AQUEOUS MIXTURES; MONOETHANOLAMINE; DIETHANOLAMINE; TRIETHANOLAMINE; TEMPERATURE DEPENDENCE;
D O I
10.1007/BF00973546
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have measured densities of binary mixtures of water with monoethanolamine (MEA), diethanolamine (DEA), and triethanolamine (TEA) over the full range of compositions and over the temperature range from 25 to 80-degrees-C. Results of these measurements have been used in calculating excess molar volumes and partial molar volumes. Knowledge of the volumetric properties of these mixtures is useful in connection with industrial treatment of acidic gases, derived excess molar volumes and partial molar volumes can be used as a basis for understanding some of the molecular interactions in water-organic mixtures.
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页码:195 / 205
页数:11
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