OPTICAL-PROPERTIES OF MANGANESE FERRITES

被引:16
作者
SIMSA, Z [1 ]
SIROKY, P [1 ]
LUKES, F [1 ]
SCHMIDT, E [1 ]
机构
[1] JE PURKYNE UNIV, FAC SCI, DEPT SOLID STATE PHYS, CS-61137 BRNO, CZECHOSLOVAKIA
来源
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS | 1979年 / 96卷 / 01期
关键词
D O I
10.1002/pssb.2220960111
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The near normal reflectance spectrum together with the data on the index of refraction and the extinction coefficient are combined in a Kramers‐Kronig analysis to obtain the spectral dependences of the real and the imaginary parts of the diagonal elements of the dielectric function of the single crystal series MnxFe3−xO4 for 0 ≦ x ≦ 1.6. One‐oscillator fit to optical constants is used to show that the main rise in absorption at about 2 eV is due to the 3d‐crystal field transitions of the Fe3+ and/or Mn2+ ions in tetrahedral sites. The anomalous behaviour of optical constants below 1 eV in iron rich Mn‐ferrites is ascribed to the presence of charge carriers (Fe2+) in octahedral sites. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA
引用
收藏
页码:137 / 144
页数:8
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