REARRANGEMENTS OF 2,6-DIARYL-3,7-DIOXABICYCLO[3.3.0]OCTANE LIGNANS REACTIONS OF PAULOWNIN AND WODESHIOL WITH TRIETHYLSILANE AND BF3-ETHERATE

被引：18

作者：

PELTER, A ^{[1
]}

WARD, RS ^{[1
]}

VENKATESWARLU, R ^{[1
]}

KAMAKSHI, C ^{[1
]}

机构：

[1] ANDHRA UNIV,POSTGRAD CTR,NUZVID 521201,INDIA

来源：

TETRAHEDRON | 1992年 / 48卷 / 35期

关键词：

D O I：

10.1016/S0040-4020(01)88261-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Paulownin on treatment with triethylsilane and BF3-etherate reacts in a similar manner to gmelinol, giving an aryltetralin as the product. In contrast, wodeshiol under the same conditions rearranges to two isomeric tetrahydropyran derivatives, the structures of which have been deduced on the basis of their H-1 and C-13 n.m.r. spectra, including NOE and spin decoupling experiments.

引用

页码：7209 / 7220

页数：12

共 4 条

[1] A GENERAL-SYNTHESIS OF 2,6-DIARYL-3,7-DIOXABICYCLO[3.3.0]OCTANE LIGNANS APPLICABLE TO UNSYMMETRICALLY SUBSTITUTED COMPOUNDS [J].