RUTHENIUM-CATALYZED OXYGENATION OF SATURATED-HYDROCARBONS BY T-BUTYLHYDROPEROXIDE

被引：51

作者：

BRESSAN, M ^{[1
]}

MORVILLO, A ^{[1
]}

ROMANELLO, G ^{[1
]}

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM INORGAN,I-35131 PADUA,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 77卷 / 03期

关键词：

D O I：

10.1016/0304-5102(92)80207-W

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Saturated hydrocarbons such as adamantane, cyclooctane, cyclohexane, hexane and heptane are oxygenated by t-butylhydroperoxide (TBHP) or hypochlorite in the presence of the homogeneous catalysts K5[Ru(H2O)PW11O39] and cis-[Ru(H2O)2(dmso)4](BF4)2. With the latter a free-radical mechanism appears to dominate when TBHP is employed, thus accounting for the remarkably high rates of alkane conversions (up to ca. 8 turnovers per minute). Hypochlorite oxygenations proceed via oxo-metal species.

引用

页码：283 / 288

页数：6

共 33 条

[1] CIS-DIHALOTETRAKIS(DIMETHYL SULFOXIDE)RUTHENIUM(II) AND TRANS-DIHALOTETRAKIS(DIMETHYL SULFOXIDE)RUTHENIUM(II) COMPLEXES (RUX2(DMSO)4, X = CL, BR) - SYNTHESIS, STRUCTURE, AND ANTITUMOR-ACTIVITY
ALESSIO, E
MESTRONI, G
NARDIN, G
ATTIA, WM
CALLIGARIS, M
SAVA, G
ZORZET, S
[J]. INORGANIC CHEMISTRY, 1988, 27 (23) : 4099 - 4106
[2] SELECTIVE OXIDATION OF ALCOHOLS BY A H2O2-RUCL3 SYSTEM UNDER PHASE-TRANSFER CONDITIONS
BARAK, G
DAKKA, J
SASSON, Y
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (15) : 3553 - 3555
[3] RUTHENIUM(III)-CATALYSED HYDROGEN-PEROXIDE OXIDATION OF ALKYL AROMATIC-COMPOUNDS UNDER PHASE-TRANSFER CONDITIONS
BARAK, G
SASSON, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (10) : 637 - 638
[4] BARNES JR, 1979, J CHEM RES M, P4301
[5] MECHANISM OF THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS BY GIF SYSTEMS - RELATIONSHIP WITH METHANE MONOOXYGENASE
BARTON, DHR
CSUHAI, E
DOLLER, D
OZBALIK, N
BALAVOINE, G
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1990, 87 (09) : 3401 - 3404
[6] OXIDATIVE CLEAVAGE OF STYRENE WITH OXYGEN CATALYZED BY PHOSPHINORUTHENIUM(II) COMPLEXES
BONALDO, M
BORIN, F
BRESSAN, M
MORVILLO, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 363 (1-2) : 175 - 179
[7] ALKENE EPOXIDATION BY RUTHENIUM(II) PHOSPHINE COMPLEXES - A KINETIC INVESTIGATION
BRESSAN, M
MORVILLO, A
[J]. INORGANIC CHEMISTRY, 1989, 28 (05) : 950 - 953
[8] SELECTIVE OXYGENATION OF ALIPHATIC ETHERS CATALYZED BY RUTHENIUM(II) COMPLEXES
BRESSAN, M
MORVILLO, A
ROMANELLO, G
[J]. INORGANIC CHEMISTRY, 1990, 29 (16) : 2976 - 2979
[9] SELECTIVE OXIDATION OF ALKANES AND ETHERS MEDIATED BY RUTHENIUM(II) COMPLEXES
BRESSAN, M
MORVILLO, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (07) : 421 - 423
[10] BRESSAN M, 1980, J CHEM SOC CHEM COMM, P650

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