ESCA APPLIED TO POLYMERS .25. PLASMA POLYMERIZATION - ESCA INVESTIGATION OF POLYMERS SYNTHESIZED BY EXCITATION OF INDUCTIVELY COUPLED RF PLASMAS IN ISOMERIC DIFLUOROETHYLENES

被引：37

作者：

CLARK, DT

SHUTTLEWORTH, D

机构：

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1979年 / 17卷 / 05期

关键词：

DIFLUOROETHYLENES;

D O I：

10.1002/pol.1979.170170507

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In the reported experimental study, the polymers produced by glow discharge from three isomeric monomers were examined by ESCA. The polymer produced from 1,1-difluoroethylene is discussed in some detail and compared with those prepared from the two 1,2-difluoroethylene isomers. Charge distributions for the neutral molecules and their radical cations are calculated within the INDO SCF MO formalism and a possible reaction scheme that involves fluoroacetylene is outlined.

引用

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页码：1317 / 1329

页数：13

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