BOUNDED ERROR ANALYSIS OF EXPERIMENTAL DISTRIBUTIONS OF RELAXATION-TIMES

被引:29
作者
COLONOMOS, P
GORDON, RG
机构
[1] Department of Chemistry, Harvard University, Cambridge
关键词
D O I
10.1063/1.438461
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A method is presented for analyzing experimental data from dielectric relaxation, acoustic relaxation, or other measurements related to a distribution of relaxation times. A consistency test is derived showing whether or not there is any distribution of relaxation times consistent with the data. For consistent data, the analysis then provides bounds on possible interpolations at frequencies between the measured points. Bounds are placed on the cumulative distribution of relaxation times and these bounds are shown to be the most precise attainable on the basis of any given set of experimental data. The analysis is illustrated by application to data" generated theoretically from some simple distributions of relaxation times and to some experimental data on dielectric relaxation. © 1979 American Institute of Physics."
引用
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页码:1159 / 1166
页数:8
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