STEREOCHEMISTRY OF 1,2-PHOTOCYCLOADDITION OF VINYLIC COMPOUNDS TO BENZENE

被引：13

作者：

ATKINS, RJ

FRAY, GI

GILBERT, A

BINSAMSUDIN, MW

STEWARD, AJK

TAYLOR, GN

机构：

[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TL,AVON,ENGLAND

[2] UNIV READING,DEPT CHEM,READING RG6 2AD,BERKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 12期

关键词：

D O I：

10.1039/p19790003196

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stereochemistry of the 1,2-photocycloaddition of benzene to acrylonitrile, methyl acrylate, methyl methacrylate, methyl vinyl ketone, ethyl vinyl ether, butyl vinyl ether, 2,3-dihydropyran, and 2,3-dihydro-1,4-dioxin has been investigated. The evidence indicates that exo-1,2-adducts are formed exclusively from all these vinylic compounds except the acrylates and methyl vinyl ketone, which gave mixtures of exo- and endo-stereoisomers.

引用

页码：3196 / 3202

页数：7

共 46 条

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