ELECTRONEGATIVITY AND COVALENT BINDING IN HOMONUCLEAR DIATOMIC-MOLECULES

被引：40

作者：

GHANTY, TK ^{[1
]}

GHOSH, SK ^{[1
]}

机构：

[1] BHABHA ATOM RES CTR,DIV HEAVY WATER,BOMBAY 400085,INDIA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 17期

关键词：

D O I：

10.1021/j100170a025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We propose a new electronegativity-based approach to covalent binding in homonuclear diatomic molecules in terms of the accumulation of electron density at the bond center during molecule formation by invoking the concepts of bond electronegativity and bond hardness. Expressions for the bond energies that are derived here are numerically tested for selected diatomic molecules.

引用

页码：6512 / 6514

页数：3

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