IDENTIFICATION OF CHLOROPHYLL TRANSFORMATION PRODUCTS IN A LAKE SEDIMENT BY COMBINED LIQUID-CHROMATOGRAPHY MASS-SPECTROMETRY

被引：51

作者：

ECKARDT, CB ^{[1
]}

KEELY, BJ ^{[1
]}

MAXWELL, JR ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,ORGAN GEOCHEM UNIT,CANTOCKS CLOSE,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

JOURNAL OF CHROMATOGRAPHY | 1991年 / 557卷 / 1-2期

基金：

英国自然环境研究理事会;

关键词：

D O I：

10.1016/S0021-9673(01)87138-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Negative-ion liquid chromatographic-mass spectrometric analysis of the pigment composition of the bottom sediment (15-20 cm) of a eutrophic lake revealed the presence of a novel series of chlorophyll transformation products, in which a series of C27-C30 sterols and stanols are esterified to a pyrophaeophorbide a nucleus of algal origin. The major components are algal-derived chlorophyll a and b degradation products, and the presence of a bacteriochlorophyll-related phaeophytin indicates the presence of anoxic conditions extending into the photic zone when the sediment was laid down.

引用

页码：271 / 288

页数：18

共 28 条

[1] ANALYSIS OF CHLOROPHYLL-A IN SEDIMENTS BY HIGH-PRESSURE LIQUID-CHROMATOGRAPHY [J].

BROWN, LM ;

HARGRAVE, BT ;

MACKINNON, MD .

CANADIAN JOURNAL OF FISHERIES AND AQUATIC SCIENCES, 1981, 38 (02) :205-214

[2]

CAPLE MB, 1978, J BIOL CHEM, V253, P6730

[3]

ECKARDT CB, 1991, ENERG FUEL, V4, P741

[4] HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY OF PLANT PIGMENTS [J].

ESKINS, K ;

SCHOLFIELD, CR ;

DUTTON, HJ .

JOURNAL OF CHROMATOGRAPHY, 1977, 135 (01) :217-220

[5] APPLICATIONS OF HIGH-PRESSURE LIQUID-CHROMATOGRAPHY AND FIELD DESORPTION MASS-SPECTROMETRY IN STUDIES OF NATURAL PORPHYRINS AND CHLOROPHYLL DERIVATIVES [J].

EVANS, N ;

GAMES, DE ;

JACKSON, AH ;

MATLIN, SA .

JOURNAL OF CHROMATOGRAPHY, 1975, 115 (02) :325-333

[6] THE STRUCTURE OF CHLOROPHYLL-C3, A NOVEL MARINE PHOTOSYNTHETIC PIGMENT [J].

FOOKES, CJR ;

JEFFREY, SW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (23) :1827-1828

[7] ANALYSIS OF PHYTOPLANKTON PIGMENTS BY HPLC BEFORE, DURING AND AFTER MASS OCCURRENCE OF THE MICROFLAGELLATE CORYMBELLUS-AUREUS DURING THE SPRING BLOOM IN THE OPEN NORTHERN NORTH-SEA IN 1983 [J].

GIESKES, WW ;

KRAAY, GW .

MARINE BIOLOGY, 1986, 92 (01) :45-52

[8] ANALYSIS OF CAROTENOID AND PORPHYRIN PIGMENTS OF GEOCHEMICAL INTEREST BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].

HAJIBRAHIM, SK ;

TIBBETTS, PJC ;

WATTS, CD ;

MAXWELL, JR ;

EGLINTON, G ;

COLIN, H ;

GUIOCHON, G .

ANALYTICAL CHEMISTRY, 1978, 50 (04) :549-553

[9] CHLOROPHYLLS .9. PREPARATION AND PURIFICATION OF SOME DERIVATIVES OF CHLOROPHYLLS A AND B [J].

HYNNINEN, PH .

ACTA CHEMICA SCANDINAVICA, 1973, 27 (05) :1771-1780

[10] EARLY CHLORIN DIAGENESIS IN A RECENT AQUATIC SEDIMENT [J].

KEELY, BJ ;

BRERETON, RG .

ORGANIC GEOCHEMISTRY, 1986, 10 (4-6) :975-980

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