OPTICAL RESOLUTION OF 1,3-DIMETHYL-5-PHENYL-DELTA-2-PYRAZOLINE BY DIASTEREOISOMERIC COMPLEX-FORMATION WITH AN OPTICALLY-ACTIVE HOST COMPOUND - X-RAY AND MOLECULAR-STRUCTURE OF THE COMPLEX

被引：15

作者：

TODA, F

TANAKA, K

INFANTES, L

FOCESFOCES, C

CLARAMUNT, RM

ELGUERO, J

机构：

[1] CSIC,INST QUIM FIS ROCASOLANO,DEPT CRISTALOG,E-28006 MADRID,SPAIN

[2] UNIV NACL EDUC DISTANCIA,DEPT QUIM ORGAN & BIOL,E-28040 MADRID,SPAIN

[3] CSIC,INST QUIM MED,E-28006 MADRID,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 14期

关键词：

D O I：

10.1039/c39950001453

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of optical resolution of a non-functionalized Delta(2)-pyrazoline is reported using (R,R)-(-)-trans-4,5-bis(hydroxydi-o-tolylmethyl)-2,2-dimethyl-1,3-dioxacyclopentane as host; the X-ray analysis carried out at 200 K shows that the crystal contains the S enantiomer of 1,3-dimethyl-5-phenyl-Delta(2)-pyrazoline.

引用

页码：1453 / 1454

页数：2

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