SYNTHESIS, SPECTROSCOPY AND X-RAY STRUCTURE OF HEXAKIS(MU-3-METHYL-4-ETHYL-1,2,4-TRIAZOLO-N-1,N-2)TETRAAQUATRICOPPER(II) HEXAKIS(TRIFLUOROMETHYLSULFONATE)

被引：42

作者：

VREUGDENHIL, W

HAASNOOT, JG

REEDIJK, J

WOOD, JS

机构：

[1] LEIDEN STATE UNIV,GORLAEUS LABS,POB 9502,2300 RA LEIDEN,NETHERLANDS

[2] UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01003

来源：

INORGANICA CHIMICA ACTA | 1990年 / 167卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)83943-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, characterization and X-ray structure determination of [Cu3(metz)6(H2O)4] (CF3SO3)6(H2O)4 is described. The compound crystallizes in the space group R3, with a = b = 14.075(3) and c = 34.655(8) Å. The complex cation consists of linear trinuclear clusters positioned on the crystallographic three-fold axis, and in which the Cu atoms are bridged by triple N1,N2-coordinating triazole ligands. The terminal copper atoms are in addition coordinated by two water molecules, and thus have a distorted tetragonal pyramidal geometry. The central copper ion is located at a three-fold inversion center and thus should exhibit dynamic Jahn-Teller behaviour. In the crystal one observes the average of three such trimers related by the three-fold axis, and due to this disorder and also to that in the triflate anions, the structure could be refined only to R = 0.17 (Rw = 0.20). The infrared and ligand-field spectroscopic data and magnetic susceptibility are in agreement with the observed structure. © 1990.

引用

收藏

页码：109 / 113

页数：5

相关论文

共 15 条

[1]

BROWN DB, 1968, INORG CHEM, V7, P932

[2] RELATIVISTIC CALCULATION OF ANOMALOUS SCATTERING FACTORS FOR X-RAYS [J].

CROMER, DT ;

LIBERMAN, D .

JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (05) :1891-&

[3] ABSORPTION CORRECTION IN CRYSTAL STRUCTURE ANALYSIS [J].

DEMEULENAER, J ;

TOMPA, H .

ACTA CRYSTALLOGRAPHICA, 1965, 19 :1014-+

[4] TRANSITION-METAL(II) THIOCYANATE COORDINATION-COMPOUNDS WITH 4-T-BUTYL-1,2,4-TRIAZOLE - STRUCTURE AND MAGNETIC-PROPERTIES [J].

GROENEVELD, LR ;

LEFEBRE, RA ;

DEGRAAFF, RAG ;

HAASNOOT, JG ;

VOS, G ;

REEDIJK, J .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 102 (01) :69-82

[5] CRYSTAL-STRUCTURE OF CATENA-POLY-(THIOCYANATO-N)CADMIUM-DI-MU-(THIOCYANATO-N)-(THIOCYANATO-N)CADMIUM-TRIS-MU-(4-T-BUTYL-1,2,4-TRIAZOLE-N1-N2) - A NEW, ALTERNATING ZIG-ZAG CHAIN CONTAINING N-BONDED, BRIDGING THIOCYANATE [J].

GROENEVELD, LR ;

VOS, G ;

VERSCHOOR, GC ;

REEDIJK, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (11) :620-621

[6]

JOHNSON CK, 1965, ORNL5138 REP

[7] CRYSTAL STRUCTURE OF BIS-[MU-(TRI-1,2,4-TRIAZOLO-N1,N2)-TRIAQUONICKEL]NICKEL HEXANITRATE DIHYDRATE, [(H2O)3(C2H3N3)3NI]2NI(NO3)6(H2O)2 [J].

REIMANN, CW ;

ZOCCHI, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1971, B 27 (MAR) :682-&

[8] THE STRUCTURE OF A,B,C,J,K,L-HEXAAQUA-D,E,F,G,H,I-HEXAKIS[MU-(4-ETHYL-1,2,4-TRIAZOLE-N1,N2)]TRIZINC(II) HEXAKIS(TRIFLUOROMETHANESULPHONATE), [ZN3(C4H7N3)6(H2O)6][CF3SO3]6 [J].

SPEK, AL ;

VOS, G .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1983, 39 (AUG) :990-993

[9] SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, AND MAGNETIC-PROPERTIES OF UNUSUAL 3,5-DIALKYL-1,2,4-TRIAZOLE COMPOUNDS CONTAINING N-BRIDGING ISOTHIOCYANATO LIGANDS - X-RAY STRUCTURE OF TRINUCLEAR BIS[(MU-THIOCYANATO-N)BIS(MU-3,5-DIETHYL-1,2,4-TRIAZOLE-N1,N2)BIS(THIOCYANATO-N)(3,5-DIETHYL-1,2,4-TRIAZOLE-N1)NICKEL(II)-N,N1,N1']NICKEL(II) DIHYDRATECT [J].

VANALBADA, GA ;

DEGRAAFF, RAG ;

HAASNOOT, JG ;

REEDIJK, J .

INORGANIC CHEMISTRY, 1984, 23 (10) :1404-1408

[10] TRANSITION-METAL(II) THIOCYANATE COORDINATION-COMPOUNDS CONTAINING 4-ALLYL-1,2,4-TRIAZOLE - STRUCTURE AND MAGNETIC-PROPERTIES [J].

VOS, G ;

HAASNOOT, JG ;

VERSCHOOR, GC ;

REEDIJK, J .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 102 (02) :187-198