REACTIVITY OF METAL-METAL BONDS - CATALYTICALLY ACTIVE COMPLEXES WITH FE-FE, FE-CO AND MN-CO BONDS

被引：26

作者：

LANGENBACH, HJ

KELLER, E

VAHRENKAMP, H

机构：

[1] Chemisches Laboratorium der Universität, D-7800 Freiburg

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 171卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)81546-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several dinuclear arsenic bridged carbonyl complexes with FeFe, MnCo, and mainly feCo bonds catalyse the dimerization of norbornadiene. The reactions can be directed exclusively to the exo-trans-exo or the Binor-S dimer. In two cases catalytically active intermediates could be isolated. Of these (CO)4Fe-AsMe2-Co(CO)2C7H8 was characterized by an X-ray crystal structure analysis which showed that the norbornadiene molecule has opened the metal metal bond. The catalysts are inactive towards other olefinic substrates. © 1979.

引用

页码：259 / 271

页数：13

共 31 条

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