OXIDATION OF STERICALLY HINDERED PHENOLS BY PERIODIC ACID

被引：19

作者：

BECKER, HD ^{[1
]}

GUSTAFSSON, K ^{[1
]}

机构：

[1] UNIV GOTHENBURG,S-40220 GOTHENBURG,SWEDEN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 03期

关键词：

D O I：

10.1021/jo01317a026

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sterically hindered phenols react smoothly with periodic acid in methanol to give, dependent on the nature of the substituent s, diphenoquinones, benzoquinones, or cyclohexadienones as major products. The formation of the various types of quinonoid compounds may be rationalized by a mechanism involving initial electrophilic substitution of the phenol by periodic acid. © 1979, American Chemical Society. All rights reserved.

引用

页码：428 / 432

页数：5

共 26 条

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