PLANARIZATION OF TETRACOORDINATE CARBON-ATOM - SYNTHESIS OF 13-OXA-14-OXO-PENTACYCLO[5.5.2.1.04,15010,15]PENTADECANE, A BRIDGED TETRAQUINACANE

被引：67

作者：

KEESE, R

PFENNINGER, A

ROESLE, A

机构：

[1] Institut Für Organische Chemie, Universität Bern, Bern, CH-3012

来源：

HELVETICA CHIMICA ACTA | 1979年 / 62卷 / 01期

关键词：

D O I：

10.1002/hlca.19790620136

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structural aspects of planoid deformation of tetracoordinate carbon atom, particularly those in annulenes with central carbon atom are discussed. [12] Annulene 11 with central carbon atom is proposed as compound with strong planoid deformation around the internal carbon centre. The synthesis of a saturated precursor 15 is described. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：326 / 334

页数：9

共 44 条

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[13]

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HAAS, G ;

PRELOG, V .

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[15]

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[16]

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[17]

HELDER R, 1973, TETRAHEDRON LETT, P4321

[18]

Hendrickson J.B., 1970, ORGANIC CHEM

[19] PLANAR TETRACOORDINATE CARBON [J].

HOFFMANN, R ;

ALDER, RW ;

WILCOX, CF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (16) :4992-&

[20]

Hoffmann R., 1971, PURE APPL CHEM, V28

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