FULLERENES AND GIANT FULLERENES - SYNTHESIS, SEPARATION, AND MASS-SPECTROMETRIC CHARACTERIZATION

被引：62

作者：

PARKER, DH

CHATTERJEE, K

WURZ, P

LYKKE, KR

PELLIN, MJ

STOCK, LM

机构：

[1] UNIV CALIF IRVINE, INST SURFACE & INTERFACE SCI, IRVINE, CA 92727 USA

[2] ARGONNE NATL LAB, DIV CHEM, ARGONNE, IL 60439 USA

来源：

CARBON | 1992年 / 30卷 / 08期

关键词：

FULLERENE SYNTHESIS; MASS SPECTROMETRY; SOOT; FULLERENE SEPARATION;

D O I：

10.1016/0008-6223(92)90060-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report a detailed procedure for the production of fullerenes and giant fullerenes in very high yield. Our high yields are obtained by a combination of fine control of the arc gap distance, optimal convection in the apparatus. and careful Soxhlet extraction with selected solvents. Our extraction and mass spectrometry results confirm the existence of giant fullerenes with masses in excess of 3000 amu. We find that 94% of the soot can be extracted in N-methyl-2-pyrrolidinone, indicating that a large portion of the soot has a molecular fullerene-type structure. We also present a new one-step method for the rapid separation of pure C60 directly from raw soot. An overview of recent results in the area of synthesis and purification of fullerenes and giant fullerenes is also presented.

引用

页码：1167 / 1182

页数：16

共 48 条

[1] CHARACTERIZATION OF THE SOLUBLE ALL-CARBON MOLECULES C60 AND C70 [J].

AJIE, H ;

ALVAREZ, MM ;

ANZ, SJ ;

BECK, RD ;

DIEDERICH, F ;

FOSTIROPOULOS, K ;

HUFFMAN, DR ;

KRATSCHMER, W ;

RUBIN, Y ;

SCHRIVER, KE ;

SENSHARMA, D ;

WHETTEN, RL .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (24) :8630-8633

[2] 2 DIFFERENT FULLERENES HAVE THE SAME CYCLIC VOLTAMMETRY [J].

ALLEMAND, PM ;

KOCH, A ;

WUDL, F ;

RUBIN, Y ;

DIEDERICH, F ;

ALVAREZ, MM ;

ANZ, SJ ;

WHETTEN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) :1050-1051

[3]

BAE YK, 1991, MATERIALS RES SOC S, P733

[4] OCCURRENCE AND FRAGMENTATION OF HIGH-MASS FULLERENES [J].

BENAMOTZ, D ;

COOKS, RG ;

DEJARME, L ;

GUNDERSON, JC ;

HOKE, SH ;

KAHR, B ;

PAYNE, GL ;

WOOD, JM .

CHEMICAL PHYSICS LETTERS, 1991, 183 (1-2) :149-152

[5] FAST ONE-STEP SEPARATION AND PURIFICATION OF BUCKMINSTERFULLERENE, C-60, FROM CARBON SOOT [J].

CHATTERJEE, K ;

PARKER, DH ;

WURZ, P ;

LYKKE, KR ;

GRUEN, DM ;

STOCK, LM .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (11) :3253-3254

[6] CHARACTERIZATION OF PRECURSORS WHICH CAUSE LIGHT INSTABILITY IN HYDROPROCESSED GAS OILS [J].

CHMIELOWIEC, J ;

FISCHER, P ;

PYBURN, CM .

FUEL, 1987, 66 (10) :1358-1363

[7] CHARACTERIZATION OF C60 AND C70 CLUSTERS [J].

COX, DM ;

BEHAL, S ;

DISKO, M ;

GORUN, SM ;

GREANEY, M ;

HSU, CS ;

KOLLIN, EB ;

MILLAR, J ;

ROBBINS, J ;

ROBBINS, W ;

SHERWOOD, RD ;

TINDALL, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (08) :2940-2944

[8]

COX DM, 1991, MATERIALS RES SOC S, P651

[9] FORMATION OF HIGH MASS CARBON CLUSTER IONS FROM LASER ABLATION OF POLYMERS AND THIN CARBON-FILMS [J].

CREASY, WR ;

BRENNA, JT .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (04) :2269-2279

[10] THE HIGHER FULLERENES - ISOLATION AND CHARACTERIZATION OF C76, C84, C90, C94, AND C70O, AN OXIDE OF D5H-C70 [J].

DIEDERICH, F ;

ETTL, R ;

RUBIN, Y ;

WHETTEN, RL ;

BECK, R ;

ALVAREZ, M ;

ANZ, S ;

SENSHARMA, D ;

WUDL, F ;

KHEMANI, KC ;

KOCH, A .

SCIENCE, 1991, 252 (5005) :548-551

← 1 2 3 4 5 →