SYNTHESIS, COORDINATION AND MAGNETIC-PROPERTIES OF A NOVEL FAMILY OF STABLE CHELATE BASED BIRADICALS - MOLECULAR-STRUCTURE OF A 2,2'-BIPYRIDINE N-OXIDE N-OXYL BIRADICAL AND ITS COPPER(II) COMPLEX

被引：50

作者：

LUNEAU, D ^{[1
]}

LAUGIER, J ^{[1
]}

REY, P ^{[1
]}

ULRICH, G ^{[1
]}

ZIESSEL, R ^{[1
]}

LEGOLL, P ^{[1
]}

DRILLON, M ^{[1
]}

机构：

[1] ECOLE EUROPEENNE HAUTES ETUD IND CHIM,IPCMS,GMI,URM 46,F-67008 STRASBOURG,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 06期

关键词：

D O I：

10.1039/c39940000741

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Multiple (aldehyde + hydroxylamine) condensation followed by mild oxidation gives the chelating N-oxide N-ox biradicals 3 and 6; both ligands gave mononuclear copper(II) and nickel(II) complexes which coordinate the two radicals and display strong antiferromagnetic coupling at low temperature.

引用

页码：741 / 742

页数：2

共 13 条

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