ELECTRONIC STATES AND RADIATIVE TRANSITIONS IN LIAR

被引：34

作者：

GU, JP

HIRSCH, G

BUENKER, RJ

PETSALAKIS, ID

THEODORAKOPOULOS, G

HUANG, MB

机构：

[1] NATL HELLEN RES FDN,INST THEORET & PHYS CHEM,GR-11635 ATHENS,GREECE

[2] UNIV SCI & TECHNOL CHINA,DEPT MODERN CHEM,HEFEI 230026,PEOPLES R CHINA

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 230卷 / 06期

关键词：

D O I：

10.1016/0009-2614(94)01198-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ab initio MRD-CI calculations have been carried out on the ground and the eight lowest excited electronic states of LiAr, correlating with excited Li atom states up to 3d D-2. The ground (X (2) Sigma(2s)) and 2 (2) Sigma(+) (2p) electronic states are repulsive while the higher excited states show shallow Rydberg minima. Rates of radiative bound-bound and bound-free transitions have been also calculated.

引用

页码：473 / 479

页数：7

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