NOVEL INORGANIC OXIDE PILLARED GAMMA-ZIRCONIUM PHOSPHATE FORMED BY INTERCALATION OF OCTAMERIC SILOXANES

被引:29
作者
CASSAGNEAU, T [1 ]
JONES, DJ [1 ]
ROZIERE, J [1 ]
机构
[1] UNIV MONTPELLIER 2, AGREGATS MOLEC & MAT INORGAN LAB, URA 79, F-34095 MONTPELLIER 5, FRANCE
关键词
D O I
10.1021/j100136a002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cross-linked materials derived from gamma-zirconium phosphate have been synthesized by the intercalation of octakis-(aminopropylsiloxane) followed by calcination. These compounds represent a novel inorganic oxide pillared gamma-zirconium phosphate, and the origin of their porosity resides in the structural characteristics of the host material. An alternative, low temperature, approach to silica pillaring is also described.
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页码:8678 / 8680
页数:3
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