INVESTIGATIONS OF THE MECHANISM OF ALTERNATING COPOLYMERIZATION WITH CHARGE-TRANSFER INTERACTION OF THE MONOMERS

被引：2

作者：

RATZSCH, M ^{[1
]}

VORWIEGER, H ^{[1
]}

STEINERT, V ^{[1
]}

机构：

[1] TH LEUNA MERSEBURG,DDR-4200 MERSEBURG,GER DEM REP

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1987年 / A24卷 / 11期

关键词：

POLYMERIZATION - Copolymerization - SODIUM COMPOUNDS;

D O I：

10.1080/00222338708076949

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The applicability of the method of Giese to the measurement of the influence of monomer reactivity is examined. The reaction of alkyl mercuric salts with sodium borohydride permits the production of alkyl (cyclohexyl and butyl) radicals. Since hydrogen radicals are present in high concentration, the addition of alkenes to the reaction mixture leads to radicals from the alkenes. Further addition of alkene (polymerization) can be nearly completely excluded in this way. The composition of the reaction products is determined by gas chromatography.

引用

页码：1333 / 1344

页数：12

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