ALLYLATION OF ALDEHYDES BY ALLYLTRIBUTYLTIN AND CROTYLTRIBUTYLTIN IN THE PRESENCE OF CATALYTIC AMOUNTS OF BU2SNCL2 COMPLEX

被引：17

作者：

YANO, K ^{[1
]}

BABA, A ^{[1
]}

MATSUDA, H ^{[1
]}

机构：

[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, 2-1 YAMADA OKA, SUITA, OSAKA 565, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 01期

关键词：

D O I：

10.1246/bcsj.65.66

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In nearly neutral media, the reaction of allylic tributyltin with aldehydes is effectively catalyzed by Bu2SnCl2 complexes. The addition of coordinative reagents and benzoyl chloride as a quencher is required of the catalytic allylation, furnishing homoallyl benzoates in good to excellent yields, where a regioreversed coupling to conventional methods using crotyltributyltin is exclusively observed.

引用

页码：66 / 70

页数：5

共 18 条

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