CONFIGURATIONALLY FIXED ALPHA-ALKOXYORGANOCOPPER REAGENTS - 1,4-ADDITION OF CYCLIC ENANTIOPURE TRANSFERABLE LIGANDS WITH COMPLETE RETENTION OF CONFIGURATION

被引：47

作者：

LINDERMAN, RJ

GRIEDEL, BD

机构：

[1] Department of Chemistry, North Carolina State University, Raleigh

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 19期

关键词：

D O I：

10.1021/jo00019a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active 4-lithio-1,3-dioxanes have been converted to the corresponding TMEDA-organocopper reagents and shown to undergo conjugate addition reactions to ethyl propiolate with complete retention of configuration.

引用

页码：5491 / 5493

页数：3

共 19 条

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