MONOCYCLIC/BICYCLIC TAUTOMERISM IN 4-HYDROXYCYCLOOCTANONES AND 4-AMINOCYCLOOCTANONES AND 4-AMINOOCTENONES

被引：5

作者：

MALPASS, JR

SMITH, C

机构：

[1] Department of Chemistry, University of Leicester, Leicester

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 02期

关键词：

D O I：

10.1016/0040-4039(92)88070-L

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

4-Hydroxycyclooctanone and 4-hydroxycyclooct-2-enone are shown to be in equilibrium with their respective bicyclic tautomers; the corresponding 4-aminocyclooctanones and -oct-2-enones have been synthesised and these amino-ketones show similar behaviour. The position of equilibrium varies with substitution (and with temperature in some cases).

引用

页码：277 / 280

页数：4

共 6 条

[1]

BARRELLE M, 1972, B SOC CHIM FR, P2016

[2] SYNTHETIC STUDIES ON THE 1-HYDROXY NORTROPANE SYSTEM - AN APPROACH TO CALYSTEGINES [J].