VIBRATIONAL SPECTRA OF PERFLUOROTOLUENE

被引：15

作者：

BAILEY, RT

HASSON, SG

机构：

[1] Department of Pure, Applied Chemistry University of Strathclyde, Glasgow, Scotland

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1968年 / A 24卷 / 12期

关键词：

D O I：

10.1016/0584-8539(68)80247-8

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The infrared (liquid and vapour) and Raman spectra (liquid) of perfluorotoluene have been measured. An assignment of the vibrational modes is proposed assuming free rotation of the -CF3 group and C2v symmetry. No evidence of an appreciable six-fold potential barrier was obtained. The interpretation of the spectra is based on the character of the observed bands and a comparison with the related molecules C6F5X (where X = F, Cl, Br and I). © 1968.

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页码：1891 / &

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