BOND SHIFT IN CYCLOOCTATETRAENE AND IN TETRAMETHYLCYCLOOCTATETRAENE

被引：22

作者：

GANIS, P

MUSCO, A

TEMUSSI, PA

机构：

[1] Istituto Chimico, Università degli Studi di Napoli, Naples

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 10期

关键词：

D O I：

10.1021/j100844a005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The bond shift isomerization of 1,3,5,7-tetramethylcycloocta-cis,cis,cis,cis-1,3,6,7-tetraene has been studied by means of a variable-temperature nmr study. The free energy of activation at 120° is 22.5 kcal/mol. The causes of the increase of the barrier with respect to that of cyclooctatetraene are briefly discussed.

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页码：3201 / &

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