A TRANS-CHELATING CHIRAL DIPHOSPHINE LIGAND - SYNTHESIS OF 2,2''-BIS[1-(DIPHENYLPHOSPHINO)ETHYL]-1,1''-BIFERROCENE AND ITS COMPLEXES WITH PLATINUM(II) AND PALLADIUM(II)

被引：118

作者：

SAWAMURA, M ^{[1
]}

HAMASHIMA, H ^{[1
]}

ITO, Y ^{[1
]}

机构：

[1] KYOTO UNIV,DEPT SYNTHET,KYOTO 60601,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)86110-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new chiral diphosphine ligand, (R,R)-(S,S)-2,2''-bis[1-(diphenylphosphino)ethyl]-1,1''-biferrocene, which possesses both central and planar elements of chirality, was synthesized. The NMR studies and molecular weight determination indicated that the ligand chelates to platinum(II) and palladium(II) in trans-manner.

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页码：593 / 596

页数：4

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