CHARACTERISTIC REACTIVITY OF RECOIL T-ATOM IN THE REACTION WITH SOLID NEOPENTANE-ISOBUTANE MIXTURES AT 77-K

被引:2
作者
ARATONO, Y
TACHIKAWA, E
MIYAZAKI, T
机构
[1] NAGOYA UNIV,FAC ENGN,DEPT SYNTHET CHEM,NAGOYA,AICHI 464,JAPAN
[2] JAPAN ATOM ENERGY RES INST,DIV CHEM,TOKAI,IBARAKI 31911,JAPAN
来源
RADIATION PHYSICS AND CHEMISTRY | 1979年 / 13卷 / 3-4期
关键词
D O I
10.1016/0146-5724(79)90058-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Reactions of recoil T atoms produced by a 6Li(n α)T reaction were studied in neo-C5H12-i-C4H10 (2 mol/100 mol of neo-C5H12) mixtures at 77 K and at 310 K. Neither the hot T atoms nor the thermal T atoms react with the solute i-C4H10 molecule at 77 K. The hot T atoms react with the solvent neo-C5H12 molecule. The results at 77 K are compared with those of H atoms in the radiolysis and the photolysis. © 1979.
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收藏
页码:115 / 118
页数:4
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