EVIDENCE FOR CYCLOPROPENE FORMATION IN THE REACTIONS OF 4,4-DIMETHYL-4-SILACYCLOHEXADIENYLIDENE

被引:14
作者
COLEMAN, B
JONES, M
机构
[1] Department of Chemistry, Princeton University Princeton
关键词
D O I
10.1016/S0022-328X(00)83220-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In the reactions of 4,4-dimethylcyclohexadienylidene no evidence for cyclopropene formation has been found. By contrast, 4,4-dimethyl-4-silacyclohexadienylidene yields a product on reaction with butadiene that is best rationalized by intramolecular cyclopropene formation. © 1979.
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页码:393 / 401
页数:9
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