SULFURATING AND COORDINATING PROPERTIES OF N,N'-THIOBISMORPHOLINE TOWARDS IRON CARBONYLS

被引：4

作者：

DIAZ, C ^{[1
]}

机构：

[1] UNIV CHILE,FAC CIENCIAS,DEPT QUIM,SANTIAGO,CHILE

来源：

POLYHEDRON | 1990年 / 9卷 / 08期

关键词：

D O I：

10.1016/S0277-5387(00)81292-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of N,N′-thiobismorpholine, {A figure is presented}, with Fe(CO)5, Fe2(CO)9, Fe3(CO)11 and [(η5-C5H5)Fe(CO)2THF]BF4 were examined. Thiobismorpholine undergoes desulphurization towards Fe(CO)5 with formation of Fe3(CO)9S2, while the novel complex Fe(CO)4{A figure is presented} was isolated and characterized from the reaction with Fe2(CO)9. On the other hand, thiobismorpholine is somewhat unreactive towards Fe3(CO)11 but it undergoes SN fission with [(η5-C5H5)Fe(CO)2THF]BF4. © 1990.

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页码：1045 / 1049

页数：5

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