NEW EVIDENCE FOR ZWITTERIONIC INTERMEDIATES IN THE WITTIG REACTION

被引：33

作者：

SCHLOSSER, M

TUONG, HB

机构：

[1] Institut de Chimie Organique, Université Rue Lausanne, CH-1005

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 08期

关键词：

D O I：

10.1002/anie.197906331

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The course of the Wittig reaction is still a topic of controversy; oxaphosphetanes 2 have been confirmed, betaines 1 not ruled out. Reaction of Ph3P⊕ C⊖(Me) CD2OLi with CH2O and that of the non‐deuterated compound with CD2O lead to the same mixture of deuterated allyl alcohols. This result indicates an equilibrium between the different oxaphosphetans, i.e. the existence of a zwitterion. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：633 / 634

页数：2

共 13 条

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[10] SCHLOSSER M, 1976, METHOD CHIMICUM, V7, P529

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