ELECTROCATALYTIC REDUCTION OF CO2 IN WATER ON A POLYMERIC [(RU-0(BPY)(CO)(2))(N)] (BPY=2,2'-BIPYRIDINE) COMPLEX IMMOBILIZED ON CARBON ELECTRODES

被引：85

作者：

COLLOMBDUNANDSAUTHIER, MN ^{[1
]}

DERONZIER, A ^{[1
]}

ZIESSEL, R ^{[1
]}

机构：

[1] ECOLE EUROPEENE HAUTES ETUD IND CHIM STRASBOURG,INST PHYS & CHIM MAT,MAT INORGAN GRP,CNRS,UMR 46,F-67008 STRASBOURG,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 02期

关键词：

D O I：

10.1039/c39940000189

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrocatalytic reduction of CO2 on a carbon/[{Ru-0(bpy)(C0)(2)}(n)] (bpy = 2,2'-bipyridine) modified electrode, prepared by electrochemical reduction of [Ru-II(bpy)(CO)(2)Cl-2], leads to the selective and quantitative formation of CO even in pure aqueous electrolyte; the stability of the modified cathode is improved by using a preformed polypyrrolic film functionalized with this complex.

引用

页码：189 / 191

页数：3

共 16 条

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