SUPRAMOLECULAR COMPLEXES OF FLEXIBLE, EXTENDED-CAVITY CALIX[4]ARENES - STRUCTURAL CHARACTERIZATION OF A MOLECULAR VENUS FLYTRAP

被引：23

作者：

ATWOOD, JL

ORR, GW

BOTT, SG

ROBINSON, KD

机构：

[1] Department of Chemistry, University of Alabama, Tuscaloosa, Alabama

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1002/anie.199310931

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Depending on the size of the guest, the calix[4]arene 1 provides either a shallow or a deep narrow cavity. Already during its synthesis, 1 binds N-(2-hydroxyethyl)-N'-methylpiperazine in a large shallow cavity. The sodium salt 2 binds CH3CO2Et in a deep cavity.

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页码：1093 / 1094

页数：2

相关论文

共 12 条

[1] Supramolecular assemblies of calix[4]arenes organized by feeble forces [J].

Atwood, Jerry L. ;

Orr, G. William ;

Hamada, Fumio ;

Bott, Simon G. ;

Robinson, Kerry D. .

SUPRAMOLECULAR CHEMISTRY, 1992, 1 (01) :15-17

[2] X-RAY-DIFFRACTION EVIDENCE FOR AROMATIC PI HYDROGEN-BONDING TO WATER [J].

ATWOOD, JL ;

HAMADA, F ;

ROBINSON, KD ;

ORR, GW ;

VINCENT, RL .

NATURE, 1991, 349 (6311) :683-684

[3] 2ND-SPHERE COORDINATION OF TRANSITION-METAL COMPLEXES BY CALIX[4]ARENES [J].

ATWOOD, JL ;

ORR, GW ;

HAMADA, F ;

VINCENT, RL ;

BOTT, SG ;

ROBINSON, KD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) :2760-2761

[4]

ATWOOD JL, 1988, ANGEW CHEM, V100, P1412

[5]

ATWOOD JL, 1988, ANGEW CHEM INT EDIT, V27, P1361

[6]

Bohmer V., 1990, CALIXARENES VERSATIL

[7] INTERCALATION OF CATIONIC, ANIONIC, AND MOLECULAR-SPECIES BY ORGANIC HOSTS - PREPARATION AND CRYSTAL-STRUCTURE OF [NH4]6[CALIX[4]ARENESULFONATE][MEOSO3].(H2O)2 [J].

BOTT, SG ;

COLEMAN, AW ;

ATWOOD, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (02) :610-611

[8]

Gutsche C. D., 1989, CALIXARENES

[9] CALIXARENES .22. SYNTHESIS, PROPERTIES, AND METAL COMPLEXATION OF AMINOCALIXARENES [J].

GUTSCHE, CD ;

NAM, KC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (18) :6153-6162

[10] NMR DETERMINATION OF ASSOCIATION CONSTANTS FOR CALIXARENE COMPLEXES - EVIDENCE FOR THE FORMATION OF A 1-2 COMPLEX WITH CALIX[8]ARENE [J].

SHINKAI, S ;

ARAKI, K ;

MANABE, O .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (21) :7214-7215