THE ORIGIN OF CARBON-MONOXIDE IN NEPTUNE ATMOSPHERE

The CO abundance in the observable atmosphere of Neptune can be plausibly explained by rapid vertical mixing from the deeper atmosphere if Neptune has a greater complement of water than Uranus. Thermochemical equilibrium and kinetic calculations reveal that Neptune must and Uranus may have about 10 times more oxygen than carbon, whereas for Jupiter and Saturn equal enrichments of carbon and oxygen are satisfactory to explain the observed CO abundances by deep vertical mixing. Relative to hydrogen and solar composition, the respective enrichment factors for carbon and oxygen are 41, 440 (Neptune); 32, less than or equal to 260 (Uranus); 6.6, 6.6 (Saturn); and 2.8, 2.8 (Jupiter). Because water ice is the most refractory ice among the ices assumed to be present in the outer solar nebula, the most massive H2O enrichment is expected for the outermost planet of this group. Thus, Neptune can indeed be regarded as the ''god of the seas.'' (C) 1994 Academic Press, Inc.