EFFECTS OF SECONDARY INTERACTIONS ON THE STEREOCHEMICAL OUTCOME OF RHODIUM(II) CARBOXYLATE CATALYZED CYCLOPROPANATION OF OLEFINS

被引:23
作者
DEMONCEAU, A
NOELS, AF
HUBERT, AJ
机构
[1] STATE UNIV LIEGE,MACROMOLEC CHEM & ORGAN CATALYSIS LAB,B-4000 LIEGE,BELGIUM
[2] STATE UNIV LIEGE,ORGAN SYNTH & CATALYSIS LAB,B-4000 LIEGE,BELGIUM
关键词
D O I
10.1016/S0040-4020(01)90524-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In cyclopropanation reactions of olefins catalysed by various dirhodium(II) tetracarboxylates, it is shown that besides the well-recognized electronic and steric effets, secondary interactions between the carbenoid complex and the substrate largely determine the stereoselectivity of the cyclopropanes. © 1990.
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页码:3889 / 3896
页数:8
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