EFFECTS OF SECONDARY INTERACTIONS ON THE STEREOCHEMICAL OUTCOME OF RHODIUM(II) CARBOXYLATE CATALYZED CYCLOPROPANATION OF OLEFINS

被引：23

作者：

DEMONCEAU, A

NOELS, AF

HUBERT, AJ

机构：

[1] STATE UNIV LIEGE,MACROMOLEC CHEM & ORGAN CATALYSIS LAB,B-4000 LIEGE,BELGIUM

[2] STATE UNIV LIEGE,ORGAN SYNTH & CATALYSIS LAB,B-4000 LIEGE,BELGIUM

来源：

TETRAHEDRON | 1990年 / 46卷 / 11期

关键词：

D O I：

10.1016/S0040-4020(01)90524-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In cyclopropanation reactions of olefins catalysed by various dirhodium(II) tetracarboxylates, it is shown that besides the well-recognized electronic and steric effets, secondary interactions between the carbenoid complex and the substrate largely determine the stereoselectivity of the cyclopropanes. © 1990.

引用

页码：3889 / 3896

页数：8

共 31 条

[1] DIASTEREOSELECTIVITY IN THE SYNTHESIS OF 3(2H)-FURANONES - TOTAL SYNTHESIS OF (+)-MUSCARINE
ADAMS, J
POUPART, MA
GRENIER, L
[J]. TETRAHEDRON LETTERS, 1989, 30 (14) : 1753 - 1756
[2] TRANSITION-METAL-CATALYZED REACTIONS OF DIAZO-COMPOUNDS .1. CYCLOPROPANATION OF DOUBLE-BONDS
ANCIAUX, AJ
HUBERT, AJ
NOELS, AF
PETINIOT, N
TEYSSIE, P
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (04) : 695 - 702
[3] TRANSITION-METAL-CATALYZED REACTIONS OF DIAZO-COMPOUNDS .2. ADDITION TO AROMATIC-MOLECULES - CATALYSIS OF BUCHNER SYNTHESIS OF CYCLOHEPTATRIENES
ANCIAUX, AJ
DEMONCEAU, A
NOELS, AF
HUBERT, AJ
WARIN, R
TEYSSIE, P
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (05) : 873 - 876
[4] STRUCTURE AND BONDING IN DIRHODIUM(II) TETRASALICYLATE
BANCROFT, DP
COTTON, FA
HAN, S
[J]. INORGANIC CHEMISTRY, 1984, 23 (16) : 2408 - 2411
[5] APPLICATIONS OF ORGANOMETALLIC REAGENTS IN BETA-LACTAM CHEMISTRY
BARRETT, AGM
STURGESS, MA
[J]. TETRAHEDRON, 1988, 44 (18) : 5615 - 5652
[6] RHODIUM(II)2,4,6-TRIARYLBENZOATES - IMPROVED CATALYSTS FOR THE SYN CYCLOPROPANATION OF Z-OLEFINS
CALLOT, HJ
METZ, F
[J]. TETRAHEDRON, 1985, 41 (20) : 4495 - 4501
[7] SYNTHESIS OF 4-ARYL-3,5-BIS(ALKOXYCARBONYL)-1,4-DIHYDROPYRAZINES
CHORVAT, RJ
RORIG, KJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (24) : 5779 - 5781
[8] ATTEMPTED AND ACCOMPLISHED SYNTHESES OF A FEW MONOFLUORINATED CHRYSANTHEMIC ACID-DERIVATIVES
COTTENS, S
SCHLOSSER, M
[J]. TETRAHEDRON, 1988, 44 (23) : 7127 - 7144
[9] CATALYTIC FUNCTIONALIZATION OF ALKANES - EVIDENCE FOR ATTRACTIVE STERIC EFFECTS IN REACTIONS OF RHODIUM CARBENOIDS
DEMONCEAU, A
NOELS, AF
HUBERT, AJ
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1989, 57 (02): : 149 - 152
[10] DEMONCEAU A, 1984, B SOC CHIM BELG, V93, P949

← 1 2 3 4 →