RECENT DEVELOPMENTS IN THE ELECTRODE-KINETICS OF SOLUTE REDOX COUPLE REACTIONS DURING ELECTROCHEMICAL DOPING OF ELECTRON-CONDUCTING POLYMERS

被引：23

作者：

LEVI, MD

PISAREVSKAYA, EY

机构：

[1] A. N. Frumkin Institute of Electrochemistry, the Academy of Sciences, the USSR, 117071 Moscow

来源：

SYNTHETIC METALS | 1991年 / 45卷 / 03期

关键词：

D O I：

10.1016/0379-6779(91)91787-B

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A phenomenological model for reactions of solute redox couples at electrodes covered with conducting polymer films has been proposed. The mechanism and kinetics of these reactions are strongly dependent on the difference in value of standard potentials of solute redox couple and polymer film under investigation. Experimental investigations of the voltammetric behaviour of various redox couples at polythiophene-, poly-p-phenylene-and poly-omicron-phenylenediamine-modified electrodes are in qualitative agreement with this model.

引用

页码：309 / 322

页数：14

共 30 条

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