ELECTROORGANIC REACTIONS ON ORGANIC ELECTRODES .16. ELECTROLYSIS USING COMPOSITE-PLATED ELECTRODES .5. INFLUENCE OF HYDROPHOBICITIES OF ANODE, SUBSTRATE AND ELECTROLYTIC SOLUTION ON ELECTROOXIDATION OF ALCOHOLS

被引：18

作者：

KUNUGI, Y ^{[1
]}

NONAKA, T ^{[1
]}

CHONG, YB ^{[1
]}

WATANABE, N ^{[1
]}

机构：

[1] APPL SCI RES INST,SAKYO KU,KYOTO 606,JAPAN

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1991年 / 318卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(91)85313-E

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In the electro-oxidation of alcohols at nickel anodes in aqueous alkaline solutions, the current efficiency for the corresponding products increased with an increase in the hydrophobicity of the anodes. An increase in the hydrophobicity of alcohol molecules also caused an increase in the efficiency at a hydrophobic anode, while, in contrast, at a hydrophilic anode the efficiency decreased with the increase in the hydrophobicity of the alcohol. However, an increase in the hydrophobicity of electrolytic solutions resulted in a decrease in the efficiency at the hydrophobic anode but not at the hydrophilic anode.

引用

页码：321 / 326

页数：6

共 5 条

[1] ELECTROLYSIS USING COMPOSITE-PLATED ELECTRODES .2. ELECTROOXIDATION OF ALCOHOLS AT A HYDROPHOBIC NICKEL POLY(TETRAFLUOROETHYLENE) COMPOSITE-PLATED ANODE [J].