REACTIONS IN HIGH BOILING SOLVENTS .I. EFFECT OF RANEY NICKEL ON STEROIDS

被引：12

作者：

BANERJEE, SK

CHAKRAVA.D

CHAKRAVA.RN

MITRA, MN

机构：

[1] Department of Chemistry, Calcutta School of Tropical Medicine

来源：

TETRAHEDRON | 1968年 / 24卷 / 21期

关键词：

D O I：

10.1016/S0040-4020(01)96837-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The effect of Raney nickel on steroids in boiling p-cymene has been studied. The following four different types of reaction have been observed: (a) dehydrogenation (oxidation) of the 3-hydroxyl group, (b) hydrogenation of 5:6-double bond, (c) isomerization of the 5β-hydrogen to 5α, and (d) dimerization. © 1968.

引用

页码：6459 / &

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