MONITORING ORGANIC-PRODUCTS OF CATALYTIC REACTIONS ON ZEOLITES BY 2-DIMENSIONAL J-RESOLVED SOLID-STATE NMR

被引:27
作者
ANDERSON, MW
KLINOWSKI, J
机构
[1] Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW, Lensfield Road
关键词
D O I
10.1016/0009-2614(90)85402-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Heteronuclear two-dimensional J-resolved 13C spectra of the products of the catalytic conversion of methanol on zeolite H-ZSM-5 can determine the number of protons attached to each carbon atom in the various organics and the details of 13C1H couplings, enabling us to make firm assignments for a number of resonances. A signal previously attributed to a mixture of n-hexane, isopentane and n-heptane, can now be unambiguously assigned to isopentane alone. © 1990.
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页码:275 / 278
页数:4
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