LOW-VALENT ORGANOTITANIUM SPECIES AND THEIR APPLICATIONS TO ORGANIC-SYNTHESIS

被引：35

作者：

DANG, Y

GEISE, HJ

机构：

[1] UNIV INSTELLING ANTWERP,DEPT CHEM,UNIV PL 1,B-2610 WILRIJK,BELGIUM

[2] SHAANXI TEACHERS UNIV,DEPT CHEM,XIAN,PEOPLES R CHINA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 405卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)83153-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Low-valent organotitanium complexes and their synthetic applications are reviewed with emphasis on carbon-carbon bond formation. The survey covers (1) reductive coupling, (2) elimination, (3) carbonyl methylenation and general alkylidenation, (4) reduction and (5) fixation and/or reduction of small molecules.

引用

收藏

页码：1 / 39

页数：39

相关论文

共 222 条

[1] A NOVEL TITANIUM-INDUCED AROMATIC DICARBONYL COUPLING - SYNTHESIS OF A CHIRAL STRAINED POLYNUCLEAR AROMATIC HYDROCARBON [J].

AGRANAT, I ;

SUISSA, MR ;

COHEN, S ;

ISAKSSON, R ;

SANDSTROM, J ;

DALE, J ;

GRACE, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (05) :381-383

[2] FIXATION AND ACTIVATION OF CO2 AND CS2 BY CP2M(PME3)2 COMPLEXES (CP=ETA-5-CYCLOPENTADIENYL - M=TI,ZR) [J].

ALT, HG ;

SCHWIND, KH ;

RAUSCH, MD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 321 (01) :C9-C12

[3] CP2TI(PME3)(C2H2), A STARTING COMPOUND FOR TITANOCENE-VINYL COMPLEXES [J].

ALT, HG ;

HERRMANN, GS ;

RAUSCH, MD .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 356 (02) :C50-C52

[4] CP2TI(PME3)(C2H2), A STARTING COMPOUND FOR CARBON-CARBON ADDITION-REACTIONS OF ALKYNES WITH CARBON-DIOXIDE, ACETONE, ACETALDEHYDE AND ETHYLENE [J].

ALT, HG ;

HERRMANN, GS ;

RAUSCH, MD ;

MALLIN, DT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 356 (02) :C53-C56

[5]

ALT HG, 1987, J ORGANOMET CHEM, V329, P61

[6] FORMATION AND REACTIVITY OF THE ETHYLENE COMPLEX CP2TIC2H4 - THE CRYSTAL-STRUCTURE OF (CP2TIET)2O [J].

ALT, HG ;

SCHWIND, KH ;

RAUSCH, MD ;

THEWALT, U .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 349 (1-2) :C7-C10

[7] ACETYLENE DERIVATIVES OF TITANOCENE [J].

ALT, HG ;

ENGELHARDT, HE ;

RAUSCH, MD ;

KOOL, LB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (12) :3717-3718

[8] MECHANISM OF TITANOCENE METALLACYCLOBUTANE CLEAVAGE AND THE NATURE OF THE REACTIVE INTERMEDIATE [J].

ANSLYN, EV ;

GRUBBS, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (16) :4880-4890

[9] PREPARATION OF ZEROVALENT DI(ETA-ARENE)TITANIUM COMPOUNDS USING TITANIUM VAPOR [J].

ANTHONY, MT ;

GREEN, MLH ;

YOUNG, D .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (14) :1419-1422

[10] HIGH-YIELD SYNTHESES AND CHARACTERIZATION OF A NEW ZIRCONOCENE(II) DICARBONYL [ZR(ETA-C5H3(SIME3)2)2(CO)2], A CONVENIENT PRECURSOR TO VARIOUS ZIRCONOCENE(II OR IV) COMPLEXES [J].

ANTINOLO, A ;

LAPPERT, MF ;

WINTERBORN, DJW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 272 (03) :C37-C39

← 1 2 3 4 5 6 7 8 9 10 →