TEMPERATURE-DEPENDENCE OF PHOTOINDUCED ANISOTROPY IN RIGID SOLUTIONS OF AZO DYES

被引:26
作者
MATEEV, V [1 ]
MARKOVSKY, P [1 ]
NIKOLOVA, L [1 ]
TODOROV, T [1 ]
机构
[1] BULGARIAN ACAD SCI,CENT LAB OPT STORAGE & PROC INFORMAT,POB 95,BU-1113 SOFIA,BULGARIA
关键词
D O I
10.1021/j100186a051
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The temperature dependence of the photoinduced dichroism and birefringence in rigid solutions of azo dyes in polymer matrices is investigated. A specific behavior of the birefringence, resulting from the temperature gradient, is demonstrated for the first time. The experimental results are described qualitatively by numerical results from a theoretical model of the photoprocesses. The influence of the temperature, changing the polymer matrix state, on the rate constants of trans-cis and cis-trans photoisomerization is shown.
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页码:3055 / 3058
页数:4
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