GENERATION OF ISOBENZOFURAN DERIVATIVES BY PYROLYSIS-GAS CHROMATOGRAPHY MASS-SPECTROMETRY

被引：4

作者：

GALLETTI, GC

WARD, RS

PELTER, A

GOUBET, D

机构：

[1] UNIV COLL SWANSEA,DEPT CHEM,SINGLETON PK,SWANSEA SA2 8PP,W GLAM,WALES

[2] CNR,CTR STUDIO CONSERVAZ FORAGGI,I-40126 BOLOGNA,ITALY

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 1992年 / 24卷 / 02期

关键词：

CYCLIZATION; CYCLOADDITION; PY-GC/MS; ISOBENZOFURAN; PYROLYSIS;

D O I：

10.1016/0165-2370(92)85025-G

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The pyrolysis behaviour of two compounds containing benzylic alcohol and acetal groups is reported. These substrates are of interest because they can readily undergo cyclisation leading to isobenzofuran derivatives. Pyrolysis-gas chromatography/mass spectrometry indicates that these reactions can occur under purely thermal conditions leading in one case to an intermediate which can, in principle, participate in cycloaddition reactions.

引用

页码：139 / 146

页数：8

共 6 条

[1] COMPREHENSIVE SYNTHETIC ROUTE TO 8 DIASTEREOMERIC PODOPHYLLUM LIGNANS [J].