Thermodynamic Studies of Dilute Aqueous Solutions of Cyclic Ethers and Simple Carbohydrates

被引：229

作者：

Franks, F. ^{[1
]}

Ravenhill, J. R. ^{[1
]}

Reid, D. S. ^{[1
]}

机构：

[1] Unilever Res Lab Colworth Welwyn, Bedford, England

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1972年 / 1卷 / 01期

关键词：

Aqueous; cyclic ethers; carbohydrates; inositols; apparent molal volume; apparent molal compressibility; density;

D O I：

10.1007/BF00648413

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Apparent molal volumes and compressibilities are reported for dilute aqueous solutions of cyclic ethers, simple carbohydrates, and related polyhydroxy compounds. The results for carbohydrates are considered in the light of two theoretical descriptions of such systems, i.e., the semiideal solution approach of Stokes and Robinson, and the McMillan-Mayer theory type of approach as employed by Kozak, Knight, and Kauzmann. It is concluded that neither model is satisfactory, and that for these solutions a specific hydration model, described in more detail in another paper, is more satisfactory.

引用

收藏

页码：3 / 16

页数：14

相关论文

共 34 条

[1] PARTIAL MOLAR VOLUMES AND MAXIMUM DENSITY EFFECTS IN ALCOHOL-WATER MIXTURES [J].

ARMITAGE, DA ;

BLANDAME.MJ ;

MORCOM, KW ;

TRELOAR, NC .

NATURE, 1968, 219 (5155) :718-&

[2]

Bale H. D., 1968, Physics and Chemistry of Liquids, V1, P181, DOI 10.1080/00319106808083797

[3] PRESSURE DEPENDENCE OF VELOCITY OF SOUND IN WATER AS A FUNCTION OF TEMPERATURE [J].

BARLOW, AJ ;

YAZGAN, E .

BRITISH JOURNAL OF APPLIED PHYSICS, 1967, 18 (05) :645-&

[4] A BIOPHYSICAL BASIS OF LIGAND-INDUCED ACTIVATION OF EXCITABLE MEMBRANES AND ASSOCIATED ENZYMES . A THERMODYNAMIC STUDY USING ACETYLCHOLINESTERASE AS A MODEL RECEPTOR [J].

BELLEAU, B ;

LAVOIE, JL .

CANADIAN JOURNAL OF BIOCHEMISTRY, 1968, 46 (11) :1397-&

[5] SYNTHESIS AND PROPERTIES OF SOME ALPHA-D-ALKYL GLUCOSIDES AND MANNOSIDES - APPARENT MOLAL VOLUMES AND SOLUBILIZATION OF NITROBENZENE IN WATER AT 25DEGREESC [J].

BROWN, GM ;

DUBREUIL, P ;

ICHHAPOR.FM ;

DESNOYER.JE .

CANADIAN JOURNAL OF CHEMISTRY, 1970, 48 (16) :2525-&

[6] STUDY OF PROTON SPIN-LATTICE RELAXATION IN WATER-DIOXAN SYSTEM [J].

CLEMETT, CJ .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (05) :761-&

[7]

COVINGTON AK, 1968, HYDROGEN BONDED SOLV

[8] PREPARATION OF METHYL D-GALACTOPYRANOSIDES [J].

FRAHN, JL ;

MILLS, JA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1965, 18 (08) :1303-&

[9] FREE VOLUME AND ENTROPY IN CONDENSED SYSTEMS .3. ENTROPY IN BINARY LIQUID MIXTURES - PARTIAL MOLAL ENTROPY IN DILUTE SOLUTIONS - STRUCTURE AND THERMODYNAMICS IN AQUEOUS ELECTROLYTES [J].

FRANK, HS ;

EVANS, MW .

JOURNAL OF CHEMICAL PHYSICS, 1945, 13 (11) :507-532

[10] MAXIMUM DENSITY EFFECTS IN DILUTE AQUEOUS SOLUTIONS OF ALCOHOLS AND AMINES [J].

FRANKS, F ;

WATSON, B .

TRANSACTIONS OF THE FARADAY SOCIETY, 1967, 63 (530P) :329-&

← 1 2 3 4 →