ALTERATION OF THE ION-OPTIC LENS CONFIGURATION TO ELIMINATE MASS-DEPENDENT MATRIX-INTERFERENCE EFFECTS IN INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRY

被引:39
作者
ROSS, BS [1 ]
HIEFTJE, GM [1 ]
机构
[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405
关键词
D O I
10.1016/0584-8547(91)80122-J
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The ion-optic lens configuration can have a substantial influence on mass-dependent matrix effects in inductively coupled plasma-mass spectrometry (ICP-MS). A laboratory-constructed instrument is used to study the influence of Sr, Ba, W, Pb and U (10 mM) on signals from Sc, Zn, Y, Ag and Cs (10-mu-M). Instrumental arrangements which did not utilize second-stage ion lenses were found to eliminate the matrix effects. With additional modifications to the third-stage lens system, the analytical utility of the system is maintained.
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页码:1263 / 1273
页数:11
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